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AI Customer ServiceHere, we propose a low-cost alkaline H 2 /Na 0.44 MnO 2 gas battery, which involves a Na 0.44 MnO 2 cathode and an H 2 gas anode in an alkaline electrolyte (6 M NaOH). The operation of
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AI Customer ServiceTo address these challenges, researchers began exploring new nonaqueous metal–gas battery paradigms by manipulating the underlying O2 redox behaviour through
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To address these challenges, researchers began exploring new nonaqueous metal–gas battery paradigms by manipulating the underlying O2 redox behaviour through electrolyte and materials design, using non-Li-metal anodes to change the nature of the solid discharge phase and improve reversibility, and using other gaseous reactants as the cathode.
The operation of the alkaline H 2 /Na 0.44 MnO 2 gas battery depends on Na + insertion/extraction in the Na 0.44 MnO 2 cathode and H + /H 2 conversion in the anode with a NiMoCo-based catalyst.
Aqueous proton batteries (APBs) are regarded as one of the most promising energy storage devices for the next-generation batteries, benefiting from its reliable safety and reasonable profitability. The non-metallic charge carriers migrate faster through the continuous water chain and exhibit considerable conductivity at low temperatures in APBs.
Additionally, within a voltage range of 0.6–1.5 V, the alkaline H 2 /Na 0.44 MnO 2 gas battery showcases a significant reversible capacity (95.2 mA h g –1 at 0.2 C) and an exceptional stability (capacity retention of 81.9% over 500 cycles at 1 C).
It was originally proposed that, in operating a metal–O 2 battery, we could use O 2 ‘for free’ from air and, thus, the weight of O 2 was omitted in early energy estimates (the reaction of Li with N 2 to give Li 3 N is not favourable enough ( Eo = 0.44 V) 25 to be accessible at typical gas cathodes) 26.
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